Constants and equations. You are responsible for knowing to what circumstance a relationship is applicable. Not all equations are needed for the exam.

Constants and units

R = 8.31447 J K^-1 mol^-1

=8.31447 x 10^-2 L bar K^-1 mol^-1

1 J = 1 kg m² s^-2

N_A = 6.022 x 10²³ mol^-1

c = 3.00 x 10⁸ m s^-1

F = 96,485 C mol^-1

h = 6.626 x 10^-34 Js

Thermodynamic relationships

DU = q + w

H = U + pV

w = -p_exDV

w = -nRT ln (V_f/V_i)

C = q/DT

DG = DH - TDS

D_rG^O = -RT ln K_eq

F = C – P + 2

Kinetics

Electrochemistry

D_rG = -nFE

D_rG^O = -nFE^O

Quantum Mechanics

I = mR²

DDE = 2hB

E_photon = hn

ln = c